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            首頁   >>   資料下載   >>   石英晶體微天平QCM金晶片的校準

            美國Gamry電化學

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            石英晶體微天平QCM金晶片的校準

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            Introduction
            This Application Note is the second in a series relating to the eQCM 10M™ and assumes that
            you have read and understand the material covered in the Application Note, Basics of a
            Quartz Crystal Microbalance.
            The purpose of this Application Note is to show the reader a simple experiment where we
            reduce Cu2+onto an Au electrode and then oxidize Cu back off. We will then use the result to
            calculate a calibration factor for the crystal. Conversely, we will show you how to calculate the
            molar mass of the species deposited using a calibration factor.
            Each crystal has a theoretical calibration factor, however, under typical experimental
            conditions, these calibration factors will vary slightly. We will use Cu2+ to calculate a
            calibration factor which could then be used in subsequent experiments on the same crystal.
            Cu2+ is reduced in a two electron reaction as shown below:

            CuSO4(aq) + 2 e- →Cu(s) + SO42-(aq)
            Our goal is to reduce Cu2+ onto an Au electrode, then use the frequency decrease and the
            charge passed to calculate a calibration factor.

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            美國Gamry電化學

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